Document Type
Article
Publication Date
10-2010
Publication Title
Acta Crystallographica. Section E - Structure Reports Online
Department
Department of Chemistry
Abstract
The title compound, C23H18N2O4S2, contains a pyrrolo group fused onto the plane of an indole ring with phenylsulfonyl and p-toluenesulfonyl groups bonded to the indole and pyrrolo rings. The angles between the mean planes of the pyrrolo- indole ring and the phenylsulfonyl and p-toluenesulfonyl rings are 73.7 (6) and 80.6 (0), respectively. The dihedral angle between the mean planes of the two benzene rings is 78.7 (4). In the crystal, both classical N—H O and non-classical C— H O intermolecular hydrogen-bonding interactions are observed, as well as weak – interactions [centroid–centroid distances = 3.6258 (8) and 3.9298 (8) A ̊ ], which contribute to the stability of the packing.
DOI
10.1107/S1600536810039425
Original Citation
Badenock JC, Jordan JA, Pelkey ET, Gribble GW, Jasinski JP. 4-Phenyl-sulfon-yl-2-(p-tolyl-sulfon-yl)-1H,8H-pyrrolo-[2,3-b]indole. Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 9;66(Pt 11):o2757-8. doi: 10.1107/S1600536810039425. PMID: 21588961; PMCID: PMC3009299.
Dartmouth Digital Commons Citation
Badenock, Jeanese C.; Jordan, Jason A.; Pelkey, Erin T.; Gribble, Gordon W.; and Jasinski, Jerry P., "4-Phenylsulfonyl-2-(p-tolylsulfonyl)-1H,8H-pyrrolo[2,3-b]indole" (2010). Dartmouth Scholarship. 416.
https://digitalcommons.dartmouth.edu/facoa/416